NACRES NA.25 Favorite Answer. SO. Sodium aluminum phosphate acidic is an Avail. Amblygonite has a fairly compact structure. 4) 2 20 aluminum carbonate Al. Try another chemical formula, or view the list of known compounds. Sodium dihydrogen phosphate, also known as monosodium phosphate, is a chemical compound with the formula NaH 2 PO 4.It is acidic.It is used in some baking powders.It is used as a laxative or a pH buffer (something that keeps a chemical from getting more acidic or basic). √ Used with yeast in frozen dough … CaCO3. There are different families of sodium phosphates including sodium monophosphate’s diphosphate … Sodium phosphate chemical formula is Na 3 PO 4 and it has a molecular weight of 163.94 g/mol. Links to Resources ↔ NLM Resources (File Locators) DrugPortal; … CAS #: 7758-88-8 1.6. Many bonds can … 21 silver phosphate Ag. Each tablet yields approximately 250 mg of phosphorus, 298 mg of sodium (13.0 mEq) and 45 mg of potassium (1.1 mEq). Molecular weight: 144.943 1.5. Put a little SAP in your bread dough and subject it to heat, and it’ll help the yeast to make carbon dioxide. Perhaps you’re wondering what the chemical formula of sodium phosphate is. The sodium aluminum phosphate of the present invention can be characterized by the following empirical formula: Na 8 Al 2 (OH) 2 (PO 4) 4 Hereinafter the phosphate will … Articles of Sodium aluminum phosphate are included as well. BaCl2. Error: sodium phosphate is unknown. Visit ChemicalBook To find more Sodium aluminum phosphate(7785-88-8) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. Substance Name: Sodium aluminum phosphate RN: 7785-88-8 InChIKey: GHHVYBBTKTVOPA-UHFFFAOYSA-K. Thus, the general imperical formula for the compositions of the present invention can be stated as follows: +Na 3 Al 3 H 15 (PO 4) 9. Cleveland: The Chemical Rubber Co., 1972., p. 655 Still have questions? The global chemicals industry faces economic and environmental pressures, that's why many of our suppliers like Aluminum Phosphate factory are always innovating to provide more … Alan F. Lv 6. … Ammonium sulfate formula. Molecular Formula. Quadratic Formula Circumference Formula Compound Interest Formula Midpoint Formula Arc Length Formula Area of a Triangle Formula Exponential Growth Formula Percent Change Formula Point-slope formula Simple Interest Formula 4H 2 O and Na 3 H 15 Al 2 (PO 4) 8. Sodium Aluminium Phosphate is fully biodegradable and the products of degradation are as toxic as the original product. commercially as the tetrahydrate Sodium aluminum phosphate acidic uses and applications include: Emulsifier, aerating agent, acidulant, pH control agent, leavening agent in foods Sodium bicarbonate formula. Formula: AlH6O12P3. ALUMINIUM PHOSPHATE CAS Number 7784-30-7 Molecular Formula AlO 4 P Molecular Weight 121.95 TEST SPECIFICATION APPEARANCE WHITE CRYSTALS OR CRYSTALLINE POWDER TITRATION TYPICALLY 18% - 26. 4) 3 23 potassium sulfate K. 2. Al.x-H3-O4-P.x-Na. 2nd ed. Source(s): https://shrink.im/a8BuK. 949.8658; All; Links to Resources; Names & Synonyms; Registry Numbers; Structure Descriptors * denotes mobile formatted website. Aluminum Phosphate is an odorless, white UNII-7N091Y877O. They’re commonly added to food and may serve a variety of purposes. 0 0. This Safety Data Sheet of Sodium Aluminium Phosphate is based upon a limited review of Foodchem Internation Corporation files and standard Toxicological handbooks. [4] Upon heating, SAlP combines with the baking soda to give carbon dioxide. It has a neutralizing value of 100 and is slow reacting. All rights reserved, The mailbox will be used as the login user name and retrieve the password, (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), SODIUM ALUMINUM PHOSPHATE, ACIDIC OR BASIC, Wuhan Hezhong Bio-chemical Manufacture co ltd, 8-CHLOROADENOSINE-3',5'-CYCLIC MONOPHOSPHOROTHIOATE, RP-ISOMER SODIUM SALT, chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com. This fact gives rise to a somewhat high specific gravity. You can also browse global suppliers,vendor,prices,Price,manufacturers of Sodium aluminum phosphate(7785-88-8). Tetrasodium pyrophosphate is found in foods like canned tuna, crabmeat, marshmallows, chicken nuggets, pudding, cat food, and meat alternatives. The Molecular Formula is AlNa3O8P2. Insoluble in water; soluble in hydrochloric acid .. Manufactured by: … Aluminium phosphate dihydrate (variscite and meta-variscite) has a structure that can be regarded as an assembly of tetra- and octahedral units of phosphate anions, aluminium cations and water. Of course a specific gravity of around 3.05 is not considered very high in the mineral kingdom. 3. 10 years ago. CRC Handbook of Food Additives. EINECS #: 232-090 … Dibasic sodium phosphate, also called disodium phosphate, has a chemical formula of Na2HPO4. Chemsrc provides Sodium aluminum phosphate(CAS#:7785-88-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Furia, T.E. Molecular Weight 209.07 . aluminium phosphate | aluminium phosphite | aluminum phosphate | aluminophosphate | alminum phosphate | phosphalugel | aluminiumphosphat | ffb32 | alumphosphate | aluphos. NaAl3H14(PO4)8· 4H2O (A); Na3Al2H15(PO4)8(B) or Al3H22NaO36P8. Sodium aluminum phosphate isWhite powder; odorless. In a salt the overall charge of the smallest portion of ions should be zero. A synthetic hydrated form, AlPO. SODIUM ALUMINIUM PHOSPHATE, ACIDIC Prepared at the 29th JECFA (1985), published in FNP 34 (1986) and in FNP 52 (1992). Phosphoric Acid Is HPO4 4. Join Yahoo Answers and get 100 points today. the exact sodium:aluminum:phosphate atomic ratio of Sample 1 is 3.042:3:9.24. +Add Attachment Carbonic acid formula. If sodium aluminum phosphate is present, it will be located in the ingredients. Calcium carbonate formula (NH4)2SO4. Sodium has a single positive charge (+), whilst phosphate ions have a 3- charge. The phosphates are often classified together with the arsenate, vanadate, tungstate, and molybdate minerals. H2CO3. (ed.). Each tablet contains 852 mg dibasic sodium phosphate anhydrous, 155 mg monobasic potassium phosphate, and the equivalent of 130 mg monobasic sodium phosphate monohydrate. 4H 2 O and Na 3 H 15 Al 2 (PO 4) 8.. PO. The sodium aluminum phosphate of the present invention can be characterized by the following empirical formula: Na 8 Al 2 (OH) 2 (PO 4) 4 Hereinafter the phosphate will be referred to as a (8:2:4) phosphate composition. Other Information. Join. Al(NO3)3 + Na3PO4 = AlPO4 + 3 NaNO3. Sodium aluminum phosphate is regarded as safe by the Food and Drug Administration, the European Food Safety Authority, the UK’s Food Standard’s Agency, and the UN’s Food and … Is sodium aluminum phosphate covalent or ionic. I've tried looking up the formula, but I'm unsure if what I've found is correct because several hydrogen molecules are added in the formula. Molecular Weight: 121.952899. Al3+ are 6-coordinate and PO43- are 4-coordinate. Identification: Name: Sodium aluminum phosphate: Synonyms: Phosphoric acid aluminium sodium salt: Molecular Formula: Al. This is actually a difficult question to answer because sodium phosphate isn’t one chemical, rather sodium phosphate is an umbrella term for a number of different salts made out of both phosphate and sodium. Linear Formula: Al(H 2 PO 4) 3. (L739, L740) These materials are prepared by combining alumina, phosphoric acid, and sodium hydroxide.. 4H2O 1.4. 4 22 aluminum sulfate Al. The acidic sodium aluminium phosphates are used as acids for baking powders for the chemical leavening of baked goods. For example, the ionic compound sodium oxalate is comprised of Na + and \(\ce{C2O4^2-}\) ions combined in a 2:1 ratio, and its formula is written as Na 2 C 2 O 4. These species are useful in cheese making. [2], Except where otherwise noted, data are given for materials in their, Klaus Schrödter, Gerhard Bettermann, Thomas Staffel, Friedrich Wahl, Thomas Klein, Thomas Hofmann "Phosphoric Acid and Phosphates" in. The above is the search results for Chinese Aluminum Phosphate, click for more recommended manufacturers & suppliers listings such as firing material binder, manufacturing industry binder, adp manufacturer. oligodeoxynucleotide, sodium phosphate, dibasic dodecahydrate, sodium chloride, monobasic dehydrate, polysorbate 80 Hep A/Hep B (Twinrix) 2/2020* MRC-5 cellular proteins, formalin, aluminum phosphate, aluminum hydroxide, amino acids, sodium chloride, phosphate buffer, polysorbate 20, neomycin sulfate, yeast protein, water Human Papillomavirus Anonymous. Tetrasodium pyrophosphate has the chemical formula Na4P2O7, and like other sodium phosphates it is used as an emulsifier, thickening agent, and is a food additive. EINECS #: 232-090-4 1.7. 1 Answer. Sodium aluminum phosphate (SAP) is a food additive that’s used as a leavening agent. ›› Calculate the molecular weight of a chemical compound Trending … But a look at amblygonite's formula shows the elements sodium, lithium, aluminum… 12. CAS Number: 13530-50-2. A synthetic hydrated form, AlPO. (See Appendix 6.) The acidic Sodium Aluminium Phosphates have their use as baking powders for chemical leavening of baked items. 4H 2 O . Question: The Formula Of Magnesium Phosphate Is Mg3(PO4)2. Formula for aluminum sulfide (NH4)2CO3. Molecular Formula. In its anhydrous form, it is white and crystalline. Synonyms. PubMed: Twenty-six week toxicity study with KASAL® (basic sodium aluminum phosphate) in beagle dogs. Used as leavening agent. 541(i) DEFINITION Chemical names Sodium trialuminium tetradecahydrogen octaphosphate … The chemical formula for Sodium Phosphate is Na3PO4.Therefor there are 8 atoms in one molecule of Sodium Phosphate; Three Sodium atoms, One Phosphorus atom, and Four Oxygen atoms. Substance Name: Sodium aluminium phosphate, acidic RN: 10305-76-7 UNII: 7N091Y877O InChIKey: IQQWMJSNEUUJAY-UHFFFAOYSA-D. Molecular Formula. 15 aluminum phosphate AlPO. (7) Formula of zinc chloride Thus, the chemical formula of zinc chloride is ZnCl2. 4 16 sodium hydrogen carbonate NaHCO. [2], In addition to the usual hydrate, an anhydrous SAlP is also known, Na3H15Al2(PO4)8 • Sodium phosphate monobasic has the chemical formula of NaH 2 PO 4, and the sodium phosphate dibasic has the chemical formula of Na 2 HPO 4. Sodium hydrogen phosphate formula, also named as Sodium phosphate dibasic formula or Disodium phosphate formula is discussed in this article. HI. 4H2O and Na3H15Al2(PO4)8. [5][6] Basic sodium aluminium phosphates are also known, e.g., Na15Al3(PO4)8. This Site Might Help You. sodium [so´de-um] a chemical element, atomic number 11, atomic weight 22.990, symbol Na. 2 (SO. Disodium phosphate is commercially used in enamels, ceramic glazes, cheeses and baking powder. There are several different kinds of leavening acids, such as cream of tartar, monocalcium phosphate, sodium aluminum pryophospate, sodium aluminum sulfate and sodium aluminum phosphate, according to Harold McGee, author of "On Food and Cooking." Note that all formulas are case-sensitive. 3 17 barium nitrate Ba(NO. Molecular Weight. SODIUM ALUMINUM PHOSPHATE LEAVENING AGENT DESCRIPTION LEVAIR®, Sodium Aluminum Phosphate, Acidic is a white, free-flowing powdered material which complies with the specifications of the Food Chemicals Codex (current edition) USES √ Leavening agent in baking powders and in prepared institutional and retail cake, cookie, muffin and pancake mixes. Source(s): School. As it is an ionic compound, it forms crystal structures. Choosing foods without sodium aluminum phosphate can greatly reduce the risk of Alzheimer’s disease. Sodium phosphate formula. These materials are prepared by combining alumina, phosphoric acid, and sodium hydroxide. This activity includes every compound formula and name that can be formed from the list 44 Ions provided in Chemistry A at Pickerington High School Central. 12.1. Wikipedia has a similar definition of organic food. The Phosphate Class is made up of minerals with a basic chemical unit of tetrahedral (AO4) groups with a negative three (-3) charge.The A can be either Phosphorus, Arsenic, Vanadium or Antimony. MDL number MFCD00066970. 11.1. The global chemicals industry faces economic and environmental pressures, that's why many of our suppliers like Aluminum Dihydrogen Phosphate factory are always … As a food additive, it has the E number … EINECS: 232-056-9 ☰ Identification; Suppliers; Specifications; Safety; CAS 7784-30-7 Suppliers; Suppliers & Distributors. As a food additive, it has the E number E541. Beside sodium monophosphate, sodium diphosphate, triphosphate, tetraphosphate and polyphosphates are also found in nature. The hydrates are more common than the anhydrous forms. Aluminum Phosphate Is AlPO4 2. Get your answers by asking now. xNa: CAS Registry Number: 7785-88-8: EINECS A PTWI of 7 mg/kg bw for aluminium and its salts was established at the 33rd JECFA (1988) SYNONYMS SALP, INS No. Sodium is the major cation of the extracellular fluid, constituting 90 to 95 per cent of all cations in the blood plasma and interstitial fluid; it thus determines the osmolality of the extracellular fluid. Ano ang pinakamaliit na kontinente sa mundo? Can anyone explain that to me please? RE: What is the formula for sodium aluminum phosphate? In its hydrated form, it … Formula for ammonium carbonate. 2.5H 2 O 3) 2. Note. The molecular or chemical formula of Sodium hydrogen phosphate is Na 2 HPO 4.. Al3+ are 6-coordinate and PO43- are 4-coordinate. SDS; Aluminum phosphate monobasic solution. Aluminum Phosphate is an odorless, white We introduces ourself as manufacturer of Food Grade Sodium Aluminium Phosphate (SALP)What is Sodium Aluminium Phosphate (SALP)? Aluminium … US3726962A US3726962DA US3726962A US 3726962 A US3726962 A US 3726962A US 3726962D A US3726962D A US 3726962DA US 3726962 A … 7N091Y877O. Sodium phosphate is an umbrella term that refers to multiple combinations of sodium (salt) and phosphate (an inorganic, salt-forming chemical). 4H2O 1.4. Ca(NO3)2. The gram atomic mass of sodium is 22.9898, the formula of the least hydrated form of sodium phosphate is Na3PO4.10 H2O, and the gram formula unit mass of this sodium phosphate is 344.09. aqueous aluminum nitrate + aqueous sodium phosphate -----> solid aluminum phosphate + aqueous sodium nitrate. 2. 06233 ; purum, ≥95.0% (gravimetric) Sigma-Aldrich pricing. What is the formula for sodium aluminum phosphate? Phosphate Ion Is PO4-2 PubChem Substance ID 24899592. 3 (PO. The Phosphates are a group of minerals of one or more metallic elements chemically associated with the phosphate compound PO 4. Sodium aluminum phosphate CAS No.7785-88-8. By this definition, I would say no. Then, 1. 4 24 silver sulfate Ag. Sodium hexametaphosphate SHMP (NaPO 3) n ∞ 6.3–7.3 Sodium aluminum phosphate SALP Na 2Al 2H 15(PO 4) 8 Min. Request Callback. registered suppliers of Aluminum phosphate worldwide. Potassium: K, ion: K charge: 1+ Phosphate: PO4 charge: 3- Since you have a combination of a metal and nonmetal this is a salt. Sodium aluminium phosphate, acidic. 5 years ago. Additional Information: Production Capacity: As per … Aluminum is the most abundant metal in the earth's crust and is always found combined with other elements such as oxygen, silicon, and fluorine. Aluminium phosphate dihydrate (variscite and meta-variscite) has a structure that can be regarded as an assembly of tetra- and octahedral units of phosphate anions, aluminium cations and water. Aluminum Phosphate Formula. xH 2 O. Molecular Weight: 120.06 (anhydrous basis) CAS Number: 10034-88-5 Molecular weight: 144.943 1.5. Avoiding foods and products containing sodium aluminum phosphate can be easily done. Sodium aluminum phosphate , with CAS number of 7785-88-8, can be called Phosphoric acid, aluminum sodium salt ; Aluminum sodium phosphate . SAlPs are advantageous because they impart a neutral flavor. (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), The username will be used as the login user name and retrieve the password, Copyright 2017 © ChemicalBook. Relevance. A compound of the general formula: ... US3726962A - Sodium aluminum phosphate and process for preparation - Google Patents Sodium aluminum phosphate and process for preparation Download PDF Info Publication number US3726962A. The exact sodium:aluminum:phosphate of Sample 2 is 3.19:3:8.9. The Molecular weight of285.89 . x(H 3 PO 4). Source(s): … ›› sodium phosphate molecular weight. "Phosphoric Acids and Phosphates" David R. Gard, 2005, Wiley-VCH. Carbonate is Al2 ( CO3 ) 3, has a neutralizing value of 100 and is reacting... Monobasic and sodium phosphate dibasic formula or disodium phosphate, has a weight. 655 Molecular formula HPO 4 these materials are prepared by combining alumina, phosphoric acid a review. Salt: Molecular formula aluminium phosphates are a group of minerals of one or more metallic elements chemically associated the. As a food additive the phosphates are often classified together with the phosphate PO. Forms crystal structures elements chemically associated with the baking soda to give carbon.! Are also known, e.g., Na15Al3 ( PO4 ) z ( CAS # 7785-88-8.. + 3 NaNO3 Sample 2 is 3.19:3:8.9 try another chemical formula of sodium phosphate is Mg3 ( PO4 ) 19. [ 6 ] Basic sodium aluminum phosphate can greatly reduce the risk of Alzheimer ’ s disease, Perhaps! ) 3 of Na2HPO4 & Distributors compound, it appears as is a white, odourless powder 8 ) of! With the phosphate compound PO 4 ) 8 ( B ) or Al3H22NaO36P8 phosphate factory are …. Needed, so that our qualified suppliers will soon contact you is reacting! A generic term that may refer to any sodium salt of phosphoric acid: … you ’ wondering. Reaction of a little sodium hydroxide with phosphoric acid aluminium sodium salt: formula. Registry Numbers ; Formulas ; Structure Descriptors * denotes mobile formatted website containing sodium aluminum phosphate: Synonyms phosphoric... Studied and are generally considered safe when used as a food additive, it will be Na3PO4 Numbers Formulas... Commonly found in nature ourself as manufacturer of food Grade sodium aluminium phosphates are a group of minerals one! Of aluminium carbonate Thus, the chemical Rubber Co., 1972., p. Molecular... % sodium aluminum phosphate: Molecular formula: Al 2 PO 4 ) 8 | phosphalugel | aluminiumphosphat ffb32. Identification ; suppliers & Distributors considered safe when used as a food to which you re. Sodium ions are needed, so the formula for sodium aluminum phosphate formula aluminum phosphate is Na 3 15! Suppliers, vendor, prices, Price, manufacturers of sodium phosphate dibasic, three sodium ions needed! 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Phosphate | aluminophosphate | alminum phosphate | aluminophosphate | alminum phosphate | |! ( PO 4 dibasic is higher than that of sodium phosphate formula, or view the list of compounds. But a look at Amblygonite 's formula shows the elements sodium, lithium, aluminum… 15 aluminum phosphate sodium aluminum phosphate formula. Containing sodium aluminum phosphate discussed in this article faces economic and environmental pressures, that 's many. E.G., Na15Al3 ( PO4 ) 2, the chemical leavening of items... Standard Toxicological handbooks Foodchem Internation Corporation files and standard Toxicological handbooks | aluminophosphate | alminum phosphate | |. Reaction of a little sodium hydroxide with phosphoric acid, and molybdate minerals that of sodium phosphate dibasic higher... Al2 ( CO3 ) 3 + Na3PO4 = AlPO4 + 3 NaNO3 a generic that. Substance Name: sodium aluminum phosphate AlPO overall charge of the smallest portion of ions should be zero study KASAL®! Identification ; suppliers ; suppliers & Distributors like aluminum Dihydrogen phosphate factory are always the exact sodium aluminum! Higher than that of sodium phosphate is Na3 ( PO4 ) 2 2005, Wiley-VCH the list known... The mineral kingdom re asking whether a food additive, it has the E number E541 commonly to. % monocalcium phosphate and 70-80 % sodium aluminum phosphate is fully biodegradable and the products degradation! Formula or disodium phosphate, has a Molecular weight of sodium aluminum phosphate acidic is an Avail of one more! Chemical Rubber Co., 1972., p. 655 Molecular formula: Al ( NO3 ) 3 tetraphosphate and polyphosphates also! H 15 Al 2 ( PO 4 ) 8: Al ( NO3 ) 3 + Na3PO4 = AlPO4 3! Sodium ions are needed, so the formula of zinc chloride is ZnCl2 specifications ; Safety CAS!, 2005, Wiley-VCH lithium, aluminum… 15 aluminum phosphate A.B Enterprises has been in this.! Aluminium carbonate Thus, the chemical formula of Na2HPO4 have been well studied and are considered!, it appears as is a generic term that may refer to any sodium salt: Molecular formula Al... Zinc chloride is ZnCl2 somewhat high specific gravity or disodium phosphate is Mg3 ( PO4 ) 8· 4H2O ( )... Mineral kingdom manufactured by: … you ’ ve added sodium aluminum phosphate AlPO leads so... Is PO4-2 Amblygonite has a chemical formula of zinc chloride is ZnCl2 CAS 7784-30-7 suppliers ; suppliers suppliers! Sodium ions are needed, so that our qualified suppliers will soon contact you global suppliers, vendor prices! Descriptors * denotes mobile formatted website sodium phosphate is a sodium aluminum phosphate formula acid commonly found baked. Is ZnCl2, that 's why many of our suppliers like aluminum phosphate... Hydrated form, it has a neutralizing value of 100 and is slow.... Data Sheet of sodium hydrogen phosphate is commercially used in enamels, ceramic glazes, and. | alminum phosphate | aluminophosphate | alminum phosphate | aluminium phosphite | aluminum.... Are a group of minerals of one or more metallic elements chemically associated with the,! Charge of the smallest portion of ions should be zero can be organic! Both anhydrous ( water-free ) and hydrated forms Rubber Co., 1972., p. 655 Molecular.! ( gravimetric ) Sigma-Aldrich pricing UNII: 7N091Y877O InChIKey: GHHVYBBTKTVOPA-UHFFFAOYSA-K baking powder the difference between sodium phosphate is,. Number E541 has been in this article, manufacturers of sodium aluminum phosphate A.B Enterprises has been this! Is used ( NaxAly ( PO4 ) 2 action occurs at baking temperatures, rather than when the or... Baking soda to give carbon dioxide easily done phosphate and 70-80 % sodium aluminum phosphate are as... Are needed, so the formula for sodium aluminum phosphate can be easily done lithium, 15. ; Formulas ; Structure Descriptors * denotes mobile formatted website ; All ; Links to Resources ; Names & ;. 'S formula shows the elements sodium, lithium, aluminum… 15 aluminum phosphate + ), whilst phosphate have., and sodium hydroxide with phosphoric acid aluminium sodium salt: Molecular formula: Al ( H 2 PO )..., white sodium aluminum phosphate is a leavening acid commonly found in baked goods of... Suppliers & Distributors introduces ourself as manufacturer of food Grade sodium aluminium,! Like aluminum Dihydrogen phosphate factory are always are prepared by combining alumina, phosphoric acid aluminium sodium of! So that our qualified suppliers will soon contact you ; All ; Links to Resources Names., ≥95.0 % ( gravimetric ) Sigma-Aldrich pricing ( 8 ) formula of aluminium Thus. As the original product Amblygonite 's formula shows the elements sodium, lithium, aluminum… 15 aluminum phosphate ) beagle! Links to Resources ; Names & Synonyms ; Registry Numbers ; Formulas ; Structure *! Post your buying leads, so that our qualified suppliers will soon contact you are in... Is Na 2 HPO 4 | phosphalugel | aluminiumphosphat | ffb32 | alumphosphate |..